Linear free-energy relationships in asymmetric catalysis
نویسندگان
چکیده
منابع مشابه
Linear free energy relationships in halogen bonds 3
Four models of halogen bonds were used to quantify this bond using the DFT B97D/6-311+G(d) computational level: para-substituted iodobenzenes, paraand meta-substituted bromobenzenes complexed with three simple Lewis bases (NH3, NCH and CNH), 1-bromo-4-substituted-bicyclo[2.2.2]octanes with NH3 and 3and 4-substituted pyridines complexed with BrCl and BrF. In addition, the combination of the para...
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It is argued that the titled non-linear effects (NLE) may arise whenever the order of the reaction in the chiral catalyst in greater than 1. In a fundamental departure from previous approaches, this is mathematically elaborated for the second order case. (NLE may also be observed if the chiral catalyst forms non-reacting dimers in a competing equilibrium; practically, however, this implies the ...
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ژورنال
عنوان ژورنال: SCIENTIA SINICA Chimica
سال: 2016
ISSN: 1674-7224
DOI: 10.1360/n032015-00240